/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

1 article(s) from Ito, Shigekazu

Theoretical studies on the intramolecular cyclization of 2,4,6-t-Bu₃C₆H₂P=C: and effects of conjugation between the P=C and aromatic moieties

Masaaki Yoshifuji and
Shigekazu Ito

Beilstein J. Org. Chem. 2014, 10, 1032–1036, doi:10.3762/bjoc.10.103

PDF

Graphical Abstract

Scheme 1: (a) The original FBW rearrangement reaction and (b) the phosphorus version of FBW rearrangement.

Jump to Scheme 1

Scheme 2: Intramolecular C–H insertion of phosphanylidenecarbene.

Jump to Scheme 2

Figure 1: Optimized structure of the transition state (TS) for the intramolecular C–H insertion of 1 [MP2(Ful...

Jump to Figure 1

Figure 2: Computationally characterized cyclization procedures of 1 affording 2 [MP2(full)/6-31G(d)]. Values ...

Jump to Figure 2

Figure 3: Displacement vectors of the transition state (ν = 216.93 i cm^–1).

Jump to Figure 3

Figure 4: Optimized structure of 2 [MP2(full)/6-31G(d)]. Bond distances (Å): P1–C1 1.678, C1–C2 1.491, P1–C3 ...

Jump to Figure 4

Figure 5: HOMO (left) and LUMO (right) of 2.

Jump to Figure 5

Album

Supp Info

Full Research Paper

Published 07 May 2014

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum

Theoretical studies on the intramolecular cyclization of 2,4,6-t-Bu3C6H2P=C: and effects of conjugation between the P=C and aromatic moieties

Theoretical studies on the intramolecular cyclization of 2,4,6-t-Bu₃C₆H₂P=C: and effects of conjugation between the P=C and aromatic moieties